Analysis of Entropic vs. Thermal Fragmentation

B. Dohmen
Jakob Curdes
P. Wagner
Eberhard R. Hilf   Phone: +49-(0)441-798-2543   Fax: +49-(0)441-798-3201
Wilfried Tuszynski   Phone: +49-(0)441-798-3203   Fax: +49-(0)441-798-3201
K. Wien


Date: 19920705

InProceedings: published in Proceedings of the 40th ASMS Conference on Mass Spectrometry and Allied Topics, Washington, DC, May 31 - June 5, 1992

A first PDMS spectrum of the highly volatile decane is presented and compared
to simulation calculations. It is inferred that fragmentation in PDMS is mainly
entropic with decane being specifically hot. In addition we compare
calculations on the formation of new compounds from the innermost zone close to
the primary ion track.

DC-Metatags done by WUFI 1.1
Metadata by Thomas Severiens on 3 December 1998
Supporting work done by Sandra Valeska Bergmann.